Not really.
Just choose Ships Worldwide. You can Block the countries you do not ship to.
BTW, since the buyer is responsible for his country's duty and sales taxes , I fail to see why an FTA would be useful. Canada has FTAs with Costa Rica and Chile too, but I'd be cautious about selling there due to poor infrastructure.
And I've had a lot of trouble with Israeli customers, who are even more entitled than the French.