If you are using the business policies, I'm not that familiar with them but I see a couple of things that might be a problem. You are trying to load two different types of measurement...imperial and metric. Are those measurements actually in inches or should they be cm? I don't know what the maximum Canada Post parcel measurements are but if those numbers are really inches, that's a fairly large parcel.
Also, the service called Canada Post Expedited is for within Canada and if you use Paypal shipping to print your labels, it is actually less expensive than Regular Parcel. The only other service called expedited is Expedited USA which of course goes to the U.S. only. You always use different services for the U.S. and other international countries. If you try to use calculated shipping for a service that doesn't go to that country or use less or more than min/max measurements, calculated shipping won't work.If your package is going to be under 2 kg, you could use small packet air for overseas but it will be fairly expensive.
It is a really good idea to do some research first to see which shipping methods are for which country so that you know what would work best for you and your customers.
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