http://www.cbsa-asfc.gc.ca/travel-voyage/pdt-pdt-eng.html
Start there.
BTW, even if duty is not applicable to your item, you will have sales taxes (GST/PST/HST). Sales tax does apply to used goods.
In addition, the shipper will probably charge a service fee for wrangling the parcel across the border.
Import charges start at $20 CDN (about $18USD)